高含硫气田集输系统增压模式优化研究

随着高含硫气田的持续开发,气井井口压力逐步低于集输压力,亟需实施集输系统增压运行。采用OLGA软件,以气液两相流、压降预测、耦合传热理论为基础,针对高含硫气田集输管网高程差、气体组分、液气比、管网全尺寸参数等工况条件,建立了复杂山地高含硫湿气集输系统生产运行的数值模型,以集输系统生产历史数据为基础,验证模型准确性并进行修正。考虑单井、多井或单线配置压缩机等情况,根据开发预测的各井压力变化情况,计算集输管网的压力分布及系统能耗,重点分析了单站增压、区域+单站增压、集输干线增压三种模式,最终优选出高含硫气田集输系统增压模式。     

空化对液膜密封流场特性及密封性能的影响

为进一步探索液膜空化对密封性能的影响，以螺旋槽液膜密封为研究对象，基于JFO空化模型及坐标变换建立其数学模型并采用有限体积法离散求解。探讨Reynolds和JFO两空化边界下的密封速度场和流量场分布规律以及空穴压力对密封性能如承载能力和摩擦扭矩等影响。结果表明：空穴区的形成具有动态性，速度矢量在空穴区内部为0，在液膜始破边界和靠近内径处的液膜重生边界上速度矢量朝向空穴区，而在靠近外径处的液膜重生边界上速度矢量远离空穴区；液膜流量场主要集中于槽区内且JFO空化边界下的流量场分布比Reynolds空化边界下值更为密集；空穴压力的增加可提升液膜承载能力但增幅较小，而对摩擦扭矩的影响可忽略不计。     

非相变固体蓄热材料的蓄放热特性

搭建了低谷电蓄能蒸汽发生换热测试系统，采用数据记录仪、Hot Disk热常数分析仪等仪器检测了刚玉球等非相变固体蓄热材料的热物性。通过实验与模拟相结合的方式，研究了粉煤灰、氧化镁、刚玉砂、刚玉球等材料的蓄放热特性。分析了蓄热材料种类和粒径大小对蓄放热特性的影响，得到了不同材料的蓄热密度和综合换热系数等关键参数。结合FLUENT非稳态模拟方法，模拟了蓄热体在不同材料粒径下的蓄热和放热温度场变化规律。结果表明：刚玉球能够提供充足连续的热量，可以作为一种性能良好的蓄热材料进行应用；随着刚玉砂粒径的增大，其蓄热密度和综合换热系数会增大，有效放热时间也会延长。     

大方坯结晶器电磁搅拌器结构优化

为改善连铸结晶器内钢液的流动状况，采用有限元法和有限容积法研究了大方坯结晶器电磁搅拌器结构对连铸结晶器内电磁场、流场和温度场分布的影响。结果表明，新型结晶器电磁搅拌器在400 A、3 Hz时产生的电磁力比传统结晶器电磁搅拌器在500 A、3 Hz时产生的电磁力更加均匀，对结晶器内钢液的扰动更强，可提高结晶器内的传热效率，有助于初始凝固坯壳和等轴晶的形成，改善方坯质量。     

Sequence-Dependent Nanofiber Structures of Phenylalanine and Isoleucine Tripeptides

The molecular design of short peptides to achieve a tailor-made functional architecture has attracted attention during the past decade but remains challenging as a result of insufficient understanding of the relationship between peptide sequence and assembled supramolecular structures. We report a hybrid-resolution model to computationally explore the sequence–structure relationship of self-assembly for tripeptides containing only phenylalanine and isoleucine. We found that all these tripeptides have a tendency to assemble into nanofibers composed of laterally associated filaments. Molecular arrangements within the assemblies are diverse and vary depending on the sequences. This structural diversity originates from (1) distinct conformations of peptide building blocks that lead to different surface geometries of the filaments and (2) unique sidechain arrangements at the filament interfaces for each sequence. Many conformations are available for tripeptides in solution, but only an extended β-strand and another resembling a right-handed turn are observed in assemblies. It was found that the sequence dependence of these conformations and the packing of resulting filaments are determined by multiple competing noncovalent forces, with hydrophobic interactions involving Phe being particularly important. The sequence pattern for each type of assembly conformation and packing has been identified. These results highlight the importance of the interplay between conformation, molecular packing, and sequences for determining detailed nanostructures of peptides and provide a detailed insight to support a more precise design of peptide-based nanomaterials.     

Investigation of the influence of iron-containing abrasives on the corrosion behaviour of the aluminium alloy AlSi1.2Mg0.4

The corrosion resistance of aluminium surfaces is closely linked to the surface state after a grinding process. For years, iron-containing abrasive materials were suspected to lead to increased corrosion susceptibility after processing of aluminium surfaces. To prove a possible correlation between the iron content of an abrasive and the corrosion behaviour of aluminium components, scientific investigations and experimentally practical corrosion tests are necessary. For the current investigation, specimens of a technical Al-Si alloy from the same batch were used. The test specimens were mechanically ground with various resin-bonded model abrasives containing different iron contents. The performed corrosion tests did not reveal a negative influence of the different iron-containing abrasives on the corrosion behaviour of the Al–Si alloy. However, the most sensitive measuring method (electrochemical noise) showed differences in the surface activity depending on the type of abrasive.     

Novel hybrid serpentine-interdigitated flow field with multi-inlets and outlets of gas flow channels for PEFC applications

In our previous study, a novel flow field design for a polymer electrolyte fuel cell (PEFC) called “Hybrid Serpentine-Interdigitated (HSI)” had been proposed. Although it was very promising in terms of performance and pressure drop, it still had a major drawback of the low oxygen concentration area. To improve its design and performance, three HSI configurations with different numbers of gas inlet and outlet, namely one inlet and one outlet HSI (1-IO HSI), one inlet and two outlets HSI (1I-2O HSI) and two inlets and two outlets HSI (2-IO HSI) were numerically investigated and compared with the conventional single channel serpentine (1S). The investigation on the cell performance and other transport behaviors has been carried out using CFD techniques via ANSYS FLUENT software. At a practical operating potential of about 0.6 V of 50 cm² PEFCs, the 2-IO HSI offered the best distributions of oxygen, current density and water due to the shorter channel length. More importantly, the 2-IO HSI could contribute to a reduction in cathode pressure drop by 90%, as compared with the 1S, resulting in the enhancement in the net power output by 6%, approximately.     

基于CFD技术优化50 L发酵罐内气体分布器

通过CFD模拟技术对50L通气搅拌发酵罐内不同气体分布器的传质混合效果进行气液双相流模拟。首先对发酵罐自带气体分布器进行流场模拟,针对模拟结果提出两种改进气体分布器。结果表明:双层环形气体分布器表现出一种较理想的混合传质效果,为此类发酵罐的优化和放大提供一种有效的技术手段。     

Crystal-field engineering of ultrabroadband mid-infrared emission in Co2+-doped nano-chalcogenide glass composites

Tunable and ultrabroadband mid-infrared (MIR) emissions in the range of 2.5–4.5 μm are firstly reported from Co²⁺-doped nano-chalcogenide (ChG) glass composites. The composites embedded with a variety of binary (ZnS, CdS, ZnSe) and ternary (ZnCdS, ZnSSe) ChG nanocrystals (NCs) can be readily obtained by a simple one-step thermal annealing method. They are highly transparent in the near- and mid-infrared wavelength region. Low-cost and commercially available Er³⁺-doped fiber lasers can be used as the excitation source. By crystal-field engineering of the embedded NCs through cation- or anion-substitution, the emission properties of Co²⁺ including its emission peak wavelength and bandwidth can be tailored in a broad spectral range. The phenomena can be accounted for by crystal-field theory. Such nano-ChG composites, perfectly filling the 3–4 μm spectral gap between the oscillations of Cr²⁺ and Fe²⁺ doped IIVI ChG crystals, may find important MIR photonic applications (e.g., gas sensing), or can be used directly as an efficient pump source for Fe²⁺: IIVI crystals which are suffering from lack of pump sources.